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Synthesis, Electrochemistry, Geometric and Electronic Structure of Oxo-Molybdenum Compounds Involved in an Oxygen Atom Transferring System
The oxygen atom transfer reactivity of Tp*MoO(2)(SPh) (1) (where Tp* = hydrotris-(3,5-dimethylpyrazol-1-yl)borate) with trimethyl phosphine (PMe(3)) has been investigated. The reaction proceed through a diamagnetic phosphoryl intermediate complex, Tp*MoO(SPh)(OPMe(3)) (2), which has been isolated an...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2396449/ https://ncbi.nlm.nih.gov/pubmed/18187198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2007.11.010 |
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