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The Influence of the Oxygen Atom Acceptor on the Reaction Coordinate and Mechanism of Oxygen Atom Transfer From the Dioxo-Mo(VI) Complex, Tp(iPr)MoO(2)(OPh), to Tertiary Phosphines
The oxygen atom transfer reactivity of the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh) (Tp(iPr) = hydrotris(3-isopropylpyrazol-1-yl)borate), with a range of tertiary phosphines (PMe(3), PMe(2)Ph, PEt(3), PBu(n)(3), PEt(2)Ph, PEtPh(2) and PMePh(2)) has been investigated. The first step in all the reacti...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2897133/ https://ncbi.nlm.nih.gov/pubmed/20433155 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic902500h |
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