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Enantioselective Homocrotylboration of Aliphatic Aldehydes

A practical route to optically pure syn-homocrotylation reagents is described, including highly diastereo-and enantioselective preparation of numerous syn-homocrotyl products, as well as several matched mismatched pairs. NMR experiments suggest that the active homocrotylating species is a cyclopropy...

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Detalhes bibliográficos
Main Authors: Lin, Hongkun, Pei, Wenbo, Wang, Hao, Houk, Kendall N., Krauss, Isaac J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3560844/
https://ncbi.nlm.nih.gov/pubmed/23256566
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311061n
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