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Fingerprints of Adiabatic versus Diabatic Vibronic Dynamics in the Asymmetry of Photoelectron Momentum Distributions
[Image: see text] When the Born–Oppenheimer approximation is valid, electrons adiabatically follow the nuclear motion in molecules. For strong nonadiabatic coupling between electronic states, one encounters a diabatic motion where the electrons remain local and do not adapt to molecular geometry cha...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2012
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3560423/ https://ncbi.nlm.nih.gov/pubmed/23378888 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz3009826 |
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