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On the Construction of Diabatic and Adiabatic Potential Energy Surfaces Based on Ab Initio Valence Bond Theory

A theoretical model is presented for deriving effective diabatic states based on ab initio self-consistent field valence bond (VBSCF) theory by reducing the multi-configurational VB Hamiltonian into an effective two-state model. We describe two computational approaches for the optimization of the ef...

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Detalhes bibliográficos
Main Authors: Song, Lingchun, Gao, Jiali
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2736346/
https://ncbi.nlm.nih.gov/pubmed/18828577
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp803050e
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