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Use of novel mutant galactosyltransferase for the bioconjugation of terminal N-Acetylglucosamine (GlcNAc) residues on live cell surface

Based on the crystal structure of bovine β4Gal-T1 enzyme, mutation of a single amino acid Y289 to L289 (Y289L) changed its donor specificity from Gal to N-acetyl-galactosamine (GalNAc). A chemoenzymatic method that uses GalNAc analogues like GalNAz or 2-keto-Gal as sugar donors with the enzyme Y289L...

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Detalhes bibliográficos
Main Authors: Mercer, Natalia, Ramakrishnan, Boopathy, Boeggeman, Elizabeth, Verdi, Luke, Qasba, Pradman K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3547369/
https://ncbi.nlm.nih.gov/pubmed/23259695
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bc300542z
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