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Cyclopropane Compatibility with Oxidative Carbocation Formation: Total Synthesis of Clavosolide A
[Image: see text] Cyclopropane-substituted allylic ethers react with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone to form oxocarbenium ions with no competitive ring cleavage. This reaction can be used for the preparation of cyclopropane-substituted tetrahydropyrans. The protocol was used as a key step...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3532433/ https://ncbi.nlm.nih.gov/pubmed/23095114 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol302744t |
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