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A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate ‘J’
The pentadentate ligand (n)Bu-P2DA (2(b), (n)Bu-P2DA = N-(1′,1′-bis(2-pyridyl)pentyl)iminodiacetate) was designed to bind an iron center in a carboxylate-rich environment similar to that found in the active sites of TauD and other α-ketoglutarate-dependent mononuclear non-heme iron enzymes. The iron...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3528080/ https://ncbi.nlm.nih.gov/pubmed/23267430 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC01044E |
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