A More Reactive Trigonal Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site

The trigonal bipyramidal high-spin (S = 2) oxoiron(IV) complex [Fe(IV)(O)(TMG(2)dien)(CH(3)CN)](2+) (7) was synthesized and spectroscopically characterized. Substitution of the CH(3)CN ligand by anions, demonstrated here for X = N(3)(−) and Cl(−), yielded further S = 2 oxoiron(IV) complexes of gener...

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Detalhes bibliográficos
Main Authors: England, Jason, Guo, Yisong, Van Heuvelen, Katherine M., Cranswick, Matthew A., Rohde, Gregory T., Bominaar, Emile L., Münck, Eckard, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3150404/
https://ncbi.nlm.nih.gov/pubmed/21739994
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2040909
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