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Inverse solvent isotope effects demonstrate slow aquo release from HIF-prolyl hydroxylase (PHD2)

Prolyl Hydroxylase Domain 2 (PHD2) is deemed a primary oxygen sensor in humans yet many details of its underlying mechanism are still not fully understood. (Fe(2+)+αKG)PHD2 is 6-coordinate, with a 2His/1Asp facial triad occupying 3 coordination sites, a bidentate α-ketoglutarate occupying two sites...

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Hlavní autoři: Flagg, Shannon C., Giri, Nitai, Pektas, Serap, Maroney, Michael J., Knapp, Michael J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3525350/
https://ncbi.nlm.nih.gov/pubmed/22747465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi300229y
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