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One-Pot Arylative Epoxidation of Ketones Employing Amphoteric Bromoperfluoroarenes
A one-pot cascade arylative epoxidation of enolizable ketones with bromopentafluorobenzene (PFPBr) and derivatives into perfluoroaryl oxiranes is reported. PFPBr is utilized as an equivalent of Br(+) and PFP(−) in this highly efficient, easily scaled up and diastereoselective epoxidation reaction, w...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3525141/ https://ncbi.nlm.nih.gov/pubmed/22173895 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201106969 |
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