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A Simple One-pot Conversion of Aldehydes and Ketones to Enals

[Image: see text] A simple and efficient method to convert aldehydes into α,β-unsaturated aldehydes with a two-carbon homologation is presented. Hydroboration of ethoxy acetylene with BH(3)•SMe(2) generates tris(ethoxyvinyl) borane. Transmetallation with diethylzinc, addition to aldehydes or ketones...

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Bibliografiske detaljer
Main Authors: Valenta, Petr, Drucker, Natalie A., Bode, Jeffrey W., Walsh, Patrick J.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2731546/
https://ncbi.nlm.nih.gov/pubmed/19419211
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9005757
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