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One-pot synthesis of epoxides from benzyl alcohols and aldehydes

A one-pot synthesis of epoxides from commercially available benzyl alcohols and aldehydes is described. The reaction proceeds through in situ generation of sulfonium salts from benzyl alcohols and their subsequent deprotonation for use in Corey–Chaykovsky epoxidation of aldehydes. The generality of...

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Détails bibliographiques
Publié dans:Beilstein J Org Chem
Auteurs principaux: Alfonzo, Edwin, Mendoza, Jesse W L, Beeler, Aaron B
Format: Artigo
Langue:Inglês
Publié: Beilstein-Institut 2018
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6142752/
https://ncbi.nlm.nih.gov/pubmed/30254694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.205
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