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Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe(2)(dithiolate)(CO)(2)(PMe(3))(4)

This investigation examines the protonation of diiron dithiolates, exploiting the new family of exceptionally electron-rich complexes Fe(2)(xdt)(CO)(2)(PMe(3))(4), where xdt is edt (ethanedithiolate, 1), pdt (propanedithiolate, 2), and adt (2)aza-1,3-propanedithiolate, 3), prepared by the photochemi...

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Main Authors: Zaffaroni, Riccardo, Rauchfuss, Thomas B., Gray, Danielle L., De Gioia, Luca, Zampella, Giuseppe
Format: Artigo
Jezik:Inglês
Izdano: 2012
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3518320/
https://ncbi.nlm.nih.gov/pubmed/23095145
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3094394
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