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Total Synthesis of Potent Antitumor Agent (−)-Lasonolide A: a Cycloaddition-based Strategy
A detailed account of the enantioselective total synthesis of (−)-lasonolide A is described. Our initial route to the top tetrahydropyran ring synthesis involved an Evans asymmetric alkylation as the key step. In itially, we rely upon a diastereoselective alkylation of an α-alkoxyacetimide derivativ...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3518312/ https://ncbi.nlm.nih.gov/pubmed/18712746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.200800164 |
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