Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity

Oxoiron(IV) species have been found to act as the oxidants in the catalytic cycles of several mononuclear nonheme iron enzymes that activate dioxygen. To gain insight into the factors that govern the oxidative reactivity of such complexes, a series of five synthetic S = 1 [Fe(IV)(O)(L(N5))](2+) comp...

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Detalhes bibliográficos
Main Authors: Wang, Dong, Ray, Kallol, Collins, Michael J., Farquhar, Erik R., Frisch, Jonathan R., Gómez, Laura, Jackson, Timothy A., Kerscher, Marion, Waleska, Arkadius, Comba, Peter, Costas, Miquel, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3515645/
https://ncbi.nlm.nih.gov/pubmed/23227304
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC21318D
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