טוען...
Catalytic Enantioselective O–Nitrosocarbonyl Aldol Reaction of β–Dicarbonyl Compounds
The first example of Cu–catalyzed asymmetric O–nitrosocarbonyl aldol reaction is described. This novel protocol allows convenient access to highly enantioenriched α–hydroxy–β–ketoesters including the antibacterial natural product kjellmanianone (up to 99% ee). MnO(2) was introduced as a mild efficie...
שמור ב:
| Main Authors: | , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2012
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3515642/ https://ncbi.nlm.nih.gov/pubmed/23106266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309311z |
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