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Catalytic Enantioselective O–Nitrosocarbonyl Aldol Reaction of β–Dicarbonyl Compounds
The first example of Cu–catalyzed asymmetric O–nitrosocarbonyl aldol reaction is described. This novel protocol allows convenient access to highly enantioenriched α–hydroxy–β–ketoesters including the antibacterial natural product kjellmanianone (up to 99% ee). MnO(2) was introduced as a mild efficie...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3515642/ https://ncbi.nlm.nih.gov/pubmed/23106266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309311z |
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