Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

[RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectiviti...

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Bibliografiske detaljer
Main Authors: Takebayashi, Satoshi, Shizuno, Tsubasa, Otani, Takashi, Shibata, Takanori
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2012
Fag:
Letter
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3511021/
https://ncbi.nlm.nih.gov/pubmed/23209521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.212
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