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Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates
[RhCp*(OAc)(2)(H(2)O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C–H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF(4)·OEt(2). A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectiviti...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3511021/ https://ncbi.nlm.nih.gov/pubmed/23209521 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.212 |
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