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Activation of Si–Si Bonds for Copper(I)-Catalyzed Conjugate Silylation

Several alkyl- and vinylsilanes were prepared through the copper(I)-catalyzed conjugate silylation of α,β-unsaturated compounds. Optimal reaction conditions were first investigated to realize the conjugate addition of a nucleophilic silicon species to poorly electrophilic acceptors such as phenylvin...

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Detalhes bibliográficos
Main Authors: Iannazzo, Laura, Molander, Gary A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3510700/
https://ncbi.nlm.nih.gov/pubmed/23204924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201200767
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