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The efficiency of DPPH as a polarising agent for DNP-NMR spectroscopy

The free radical 2,2-diphenyl-1-pycrylhydrazyl (DPPH) was tested as a polarising agent for fast dissolution dynamic nuclear polarisation (DNP) NMR spectroscopy. DPPH was found to be reasonably soluble in sulfolane and the optimum concentration for DNP is 20–40 mM depending upon whether short polaris...

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Detalhes bibliográficos
Main Authors: Lumata, Lloyd, Merritt, Matthew, Khemtong, Chalermchai, Ratnakar, S. James, van Tol, Johan, Yu, Lu, Song, Likai, Kovacs, Zoltan
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3507463/
https://ncbi.nlm.nih.gov/pubmed/23205273
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2RA21853D
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