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Dissolution DNP-NMR spectroscopy using galvinoxyl as a polarizing agent

The goal of this work was to test feasibility of using galvinoxyl (2,6-di-tert-butyl-α-(3,5- di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy) as a polarizing agent for dissolution dynamic nuclear polarization (DNP) NMR spectroscopy. We have found that galvinoxyl is reasonably soluble in...

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Detalhes bibliográficos
Main Authors: Lumata, Lloyd L., Merritt, Matthew E., Malloy, Craig R., Sherry, A. Dean, van Tol, Johan, Song, Likai, Kovacs, Zoltan
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3552151/
https://ncbi.nlm.nih.gov/pubmed/23246650
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2012.11.006
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