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Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions

Pd-catalyzed aerobic oxidative coupling of vinylboronic acids and electronically unbiased alkyl olefins provides regioselective access to 1,3-disubstituted conjugated dienes. Catalyst-controlled regioselectivity is achieved by using 2,9-dimethylphenanthroline as a ligand. The observed regioselectivi...

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Main Authors: Zheng, Changwu, Wang, Dian, Stahl, Shannon S.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3495987/
https://ncbi.nlm.nih.gov/pubmed/22998540
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307371w
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