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Regioselective Aerobic Oxidative Heck Reactions with Electronically Unbiased Alkenes: Efficient Access to α-Alkyl Vinylarenes

Branched-selective oxidative Heck coupling reactions have been developed between arylboronic acids and electronically unbiased terminal alkenes. The reactions exhibit high catalyst-controlled regioselectivity favoring the less common branched isomer. The reactions employ a catalyst composed of Pd(TF...

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Pubblicato in:Chem Commun (Camb)
Autori principali: Zheng, Changwu, Stahl, Shannon S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4522933/
https://ncbi.nlm.nih.gov/pubmed/26166679
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc05312a
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