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Catalyic Double Stereoinduction in Asymmetric Allylic Alkylation of Oxindoles

A highly regio-, diastereo-, and enantioselective allylic alkylation reaction of 3-monosubstituted oxindoles catalyzed by molybdenum is described. The reaction is affected by the electronic and steric variations of the nucleophile. The use of appropriate N-protecting group is particularly important...

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Hlavní autoři: Trost, Barry M., Zhang, Yong
Médium: Artigo
Jazyk:Inglês
Vydáno: 2010
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3488305/
https://ncbi.nlm.nih.gov/pubmed/20013766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.200902770
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