Benzocyclobutene—o-xylylene valence tautomerization: Oxygen and sulfur analogs
Gas phase pyrolysis of o-hydroxybenzyl alcohol at 750°C gave o-quinonemethide, which, on isolation, formed a mixture of the corresponding dimer and trimer. However, pyrolysis of o-hydroxy-[1-(4-pentenyl)]benzyl alcohol permitted intramolecular trapping of the intermediate o-quinonemethide, giving 3,...
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| Published in: | Proc Natl Acad Sci U S A |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
National Academy of Sciences
1980
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC348578/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592792/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.77.4.1732 |
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