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Benzocyclobutene—o-xylylene valence tautomerization: Oxygen and sulfur analogs

Gas phase pyrolysis of o-hydroxybenzyl alcohol at 750°C gave o-quinonemethide, which, on isolation, formed a mixture of the corresponding dimer and trimer. However, pyrolysis of o-hydroxy-[1-(4-pentenyl)]benzyl alcohol permitted intramolecular trapping of the intermediate o-quinonemethide, giving 3,...

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Autors principals: Mao, Yuh-Lin, Boekelheide, V.
Format: Artigo
Idioma:Inglês
Publicat: 1980
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC348578/
https://ncbi.nlm.nih.gov/pubmed/16592792
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