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Benzocyclobutene—o-xylylene valence tautomerization: Oxygen and sulfur analogs

Gas phase pyrolysis of o-hydroxybenzyl alcohol at 750°C gave o-quinonemethide, which, on isolation, formed a mixture of the corresponding dimer and trimer. However, pyrolysis of o-hydroxy-[1-(4-pentenyl)]benzyl alcohol permitted intramolecular trapping of the intermediate o-quinonemethide, giving 3,...

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Detalles Bibliográficos
Publicado en:Proc Natl Acad Sci U S A
Autores principales: Mao, Yuh-Lin, Boekelheide, V.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 1980
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Acceso en línea:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC348578/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592792/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.77.4.1732
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