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Formation, Spectroscopic Characterization, and Solution Stability of an [Fe(4)S(4)](2+) Cluster Derived from a β-Cyclodextrin Dithiolate

The formation and solution properties, including stability in mixed aqueous-Me(2)SO media, have been investigated for an [Fe(4)S(4)](2+) cluster derived from a β-cyclodextrin (CD) dithiolate. Clusters of the type [Fe(4)S(4)(SAr)(4)](2−) (Ar = Ph, C(6)H(4)-3-F) are generated in Me(2)SO by redox react...

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Detalhes bibliográficos
Main Authors: Lo, Wayne, Zhang, Ping, Ling, Chang-Chun, Huang, Shaw, Holm, R. H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3483649/
https://ncbi.nlm.nih.gov/pubmed/22934734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301324u
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