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Formation, Spectroscopic Characterization, and Solution Stability of an [Fe(4)S(4)](2+) Cluster Derived from a β-Cyclodextrin Dithiolate
The formation and solution properties, including stability in mixed aqueous-Me(2)SO media, have been investigated for an [Fe(4)S(4)](2+) cluster derived from a β-cyclodextrin (CD) dithiolate. Clusters of the type [Fe(4)S(4)(SAr)(4)](2−) (Ar = Ph, C(6)H(4)-3-F) are generated in Me(2)SO by redox react...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3483649/ https://ncbi.nlm.nih.gov/pubmed/22934734 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301324u |
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