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(1)H-ENDOR Evidence for a Hydrogen Bonding Interaction that Modulates the Reactivity of a Non-heme Fe(IV)=O Unit
We report that a novel use of 35 GHz (1)H-ENDOR spectroscopy establishes the presence in 1 of an Fe(IV)=O···H–O–Fe(III) hydrogen bond predicted by DFT computations to generate a six-membered-ring core for 1. The H-bond rationalizes the difference in C–H bond cleavage reactivity between 1 and 4(OCH(3...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3482979/ https://ncbi.nlm.nih.gov/pubmed/22984805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic3015783 |
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