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Synthesis of a novel chemotype via sequential metal-catalyzed cycloisomerizations
Sequential cycloisomerizations of diynyl o-benzaldehyde substrates to access novel polycyclic cyclopropanes are reported. The reaction sequence involves initial Cu(I)-mediated cycloisomerization/nucleophilic addition to an isochromene followed by diastereoselective Pt(II)-catalyzed enyne cycloisomer...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3458758/ https://ncbi.nlm.nih.gov/pubmed/23019468 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.153 |
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