Palladium-catalyzed substitution of (coumarinyl)methyl acetates with C-, N-, and S-nucleophiles

The palladium-catalyzed nucleophilic substitution of (coumarinyl)methyl acetates is described. The reaction proceeds though a palladium π-benzyl-like complex and allows for many different types of C-, N-, and S-nucleophiles to be regioselectively added to the biologically active coumarin motif. This...

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Bibliographic Details
Main Authors: Chattopadhyay, Kalicharan, Fenster, Erik, Grenning, Alexander J, Tunge, Jon A
Format: Artigo
Language:Inglês
Published: Beilstein-Institut 2012
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3458738/
https://ncbi.nlm.nih.gov/pubmed/23019448
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.133
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