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Continuum of Mechanisms for Nucleophilic Substitutions of Cyclic Acetals

[Image: see text] The effect of nucleophile strength on diastereoselectivity in the nucleophilic substitution of cyclic acetals was explored. Stereoselectivity remained constant and high as nucleophilicity increased until a threshold value was reached. Beyond this point, however, selection of Lewis...

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Bibliografski detalji
Glavni autori: Krumper, Jennifer R., Salamant, Walter A., Woerpel, K. A.
Format: Artigo
Jezik:Inglês
Izdano: 2008
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2664297/
https://ncbi.nlm.nih.gov/pubmed/18844363
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8019956
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