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Using neighboring-group participation for acyclic stereocontrol in diastereoselective substitution reactions of acetals
Neighboring-group participation of an ester enabled stereocontrol in substitution reactions of acyclic acetals. The ester group formed a trans-fused dioxolenium ion intermediate, which underwent a substitution reaction at the acetal carbon atom to afford the product with high diastereoselectivity. N...
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| Publicado no: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7337985/ https://ncbi.nlm.nih.gov/pubmed/32392075 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01166 |
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