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Correlations Between Nucleophilicities and Selectivities in the Substitutions of Tetrahydropyran Acetals
Selectivities that deviate from S(N)1 stereoelectronic models in the nucleophilic substitutions of tetrahydropyran acetals were investigated. When weak nucleophiles were employed, stereoselectivities conformed to known S(N)1 stereoelectronic models. In contrast, stereoselectivities in the substituti...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4037909/ https://ncbi.nlm.nih.gov/pubmed/19813702 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901639b |
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