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Asymmetric total synthesis of smyrindiol employing an organocatalytic aldol key step
The first organocatalytic asymmetric synthesis of smyrindiol, by using an (S)-proline catalyzed enantioselective intramolecular aldol reaction as the key step, is described. Smyrindiol was synthesized from commercially available 2,4-dihydroxybenzaldehyde in 15 steps, with excellent stereoselectivity...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3458728/ https://ncbi.nlm.nih.gov/pubmed/23019438 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.123 |
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