Rotational barrier of a molybdenum-molybdenum quadruple bond
The synthesis and characterization of molybdenum(II) porphyrin dimers containing unbridged metal-metal quadruple bonds are presented. Variable temperature 300 MHz (1)H NMR studies of meso-substituted derivatives provide novel solution evidence for both the existence of quadruple bonds and for a barr...
Furkejuvvon:
| Publikašuvnnas: | Proc Natl Acad Sci U S A |
|---|---|
| Váldodahkkit: | , |
| Materiálatiipa: | Artigo |
| Giella: | Inglês |
| Almmustuhtton: |
National Academy of Sciences
1984
|
| Fáttát: | |
| Liŋkkat: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC345112/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593459/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.81.8.2592 |
| Fáddágilkorat: |
Eai fáddágilkorat, Lasit vuosttaš fáddágilkora!
|