Rotational barrier of a molybdenum-molybdenum quadruple bond
The synthesis and characterization of molybdenum(II) porphyrin dimers containing unbridged metal-metal quadruple bonds are presented. Variable temperature 300 MHz (1)H NMR studies of meso-substituted derivatives provide novel solution evidence for both the existence of quadruple bonds and for a barr...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Principais autores: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1984
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC345112/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593459/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.81.8.2592 |
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