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Hydrogen Donor-Acceptor Fluctuations from Kinetic Isotope Effects: A Phenomenological Model
Kinetic isotope effects (KIEs) and their temperature dependence can probe the structural and dynamic nature of enzyme-catalyzed proton or hydride transfers. The molecular interpretation of their temperature dependence requires expensive and specialized QM/MM calculations to provide a quantitative mo...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3448806/ https://ncbi.nlm.nih.gov/pubmed/22857146 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi300613e |
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