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Asymmetric catalytic synthesis of the proposed structure of trocheliophorolide B

A concise catalytic asymmetric synthesis of the proposed structure of Trocheliophorolide B is reported. The synthetic sequence notably features an asymmetric acetaldehyde alkynylation, Ru-catalyzed alder-ene reaction and Zn-ProPhenol ynone aldol condensation. Comparison with the reported data sugges...

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Detalhes bibliográficos
Main Authors: Trost, Barry. M., Quintard, Adrien
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3439167/
https://ncbi.nlm.nih.gov/pubmed/22913543
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol302074h
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