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EPR/ENDOR, Mössbauer, and Quantum Chemical Investigation of Di-iron Complexes Mimicking the Active Oxidized State of [FeFe] Hydrogenase
Understanding the catalytic process of the heterolytic splitting and formation of molecular hydrogen is one of the key topics for the development of a future hydrogen economy. With an interest in elucidating the enzymatic mechanism of the [Fe(2)(S(2)C(2)H(4)NH)(CN)(2)(CO)(2)(µ-CO)] active center uni...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2012
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3420818/ https://ncbi.nlm.nih.gov/pubmed/22800196 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic3013766 |
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