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Causation in a Cascade: The Origins of Selectivities in Intramolecular Nitrone Cycloadditions

The factors controlling chemo-, regio-, and stereoselectivity in a cascade of reactions starting from a bis(cyanoalkenyl)oxime and proceeding via nitrone cycloadditions, have been unravelled through a series of density functional calculations with several different functionals. Both kinetic and ther...

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Detalhes bibliográficos
Main Authors: Krenske, Elizabeth H., Agopcan, Sesil, Aviyente, Viktorya, Houk, K. N., Johnson, Brian A., Holmes, Andrew B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3413729/
https://ncbi.nlm.nih.gov/pubmed/22788115
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300002k
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