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Nitrone Cycloadditions of 1,2-Cyclohexadiene
We report the first 1,3-dipolar cycloadditions of 1,2-cyclohexadiene, a rarely exploited strained allene. 1,2-Cyclohexadiene is generated in situ under mild conditions and trapped with nitrones to give isoxazolidine products in synthetically useful yields. The reactions occur regioselectively and ex...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4899974/ https://ncbi.nlm.nih.gov/pubmed/26854652 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b13304 |
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