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Synthetic studies toward (+)-cortistatin A
We describe herein the synthesis of a late-stage intermediate en route to cortistatin A. Key transformations included a Snieckus-like cascade sequence culminating in a 6π-electrocyclization, an alkylative dearomatization, and the stereoselective functionalization of the cortistatin A-ring. While the...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3413295/ https://ncbi.nlm.nih.gov/pubmed/22879684 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.10.026 |
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