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Transition-Metal Catalyzed Synthesis of Aspergillide B: An Alkyne Addition Strategy
[Image: see text] A catalytic enantioselective formal total synthesis of aspergillide B is reported. This linchpin synthesis was enabled by the development of new conditions for Zn-ProPhenol catalyzed asymmetric alkyne addition. This reaction was used in conjunction with ruthenium-catalyzed trans-hy...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3407809/ https://ncbi.nlm.nih.gov/pubmed/22356535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300200m |
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