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Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene Boranes
Treatment of alkenes such as 3-hexene, 3-octene, and 1-cyclohexyl-1-butene with the N-heterocyclic carbene-derived borane 2 and catalytic HNTf(2) effects hydroboration at room temperature. With 3-hexene, surprisingly facile migration of the boron atom from C3 of the hexyl group to C2 was observed ov...
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| Autors principals: | , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3405176/ https://ncbi.nlm.nih.gov/pubmed/22713106 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305061c |
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