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Weakly Stabilized Primary Borenium Cations and their Dicationic Dimers
Hydride abstraction from monocationic hydride bridged salts [H(H(2)B–L)(2)](+) [B(C(6)F(5))(4)](−) (L = Lewis base) generates an observable primary borenium cation for L = iPr(2)NEt, but with L = Me(3)N, Me(2)NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed.
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3857331/ https://ncbi.nlm.nih.gov/pubmed/24087933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407458k |
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