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CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF(3) and BH(3)
In situ formation of two cyclic (alkyl) (amino) carbenes (CAACs) followed by addition of BF(3)•Et(2)O provided the first two examples of CAAC–BF(3) complexes: 1-(2,6-diisopropylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene trifluoroborane, and 2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2956467/ https://ncbi.nlm.nih.gov/pubmed/20978616 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.82 |
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