CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF(3) and BH(3)

In situ formation of two cyclic (alkyl) (amino) carbenes (CAACs) followed by addition of BF(3)•Et(2)O provided the first two examples of CAAC–BF(3) complexes: 1-(2,6-diisopropylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene trifluoroborane, and 2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro...

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Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Monot, Julien, Fensterbank, Louis, Malacria, Max, Lacôte, Emmanuel, Geib, Steven J, Curran, Dennis P
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Beilstein-Institut 2010
Gaiak:
Full Research Paper
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2956467/
https://ncbi.nlm.nih.gov/pubmed/20978616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.82
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